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Triphen-yl(prop-2-yn-1-yl)silane.

ABSTRACT: In the title compound, C(21)H(18)Si, the coordination geometry around the Si atom is a slightly distorted tetra-hedron with C-Si-C angles in the range 106.05?(11) to 110.58?(10) ° and Si-C bond lengths in the range 1.855?(2) to 1.883?(3)?Å. The alkyne C-C bond length is 1.167?(4)?Å. The dihedral angles between the three phenyl rings are 63.89?(7), 86.38?(7) and 70.51?(8)°. In the crystal, mol-ecules inter-act only by van der Waals forces.

SUBMITTER: Nelson B

PROVIDER: S-EPMC3275207 | biostudies-literature | 2012 Feb

REPOSITORIES: biostudies-literature

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Triphen-yl(prop-2-yn-1-yl)silane.

Nelson Björn B Schulte Michaela M Strohmann Carsten C Preut Hans H Hiersemann Martin M

Acta crystallographica. Section E, Structure reports online 20120118 Pt 2

In the title compound, C(21)H(18)Si, the coordination geometry around the Si atom is a slightly distorted tetra-hedron with C-Si-C angles in the range 106.05 (11) to 110.58 (10) ° and Si-C bond lengths in the range 1.855 (2) to 1.883 (3) Å. The alkyne C-C bond length is 1.167 (4) Å. The dihedral angles between the three phenyl rings are 63.89 (7), 86.38 (7) and 70.51 (8)°. In the crystal, mol-ecules inter-act only by van der Waals forces. ...[more]

PMID: 22347063

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