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Ethyl 2-(1,3-benzodioxol-5-yl)-1-[3-(2-oxopyrrolidin-1-yl)prop-yl]-1H-benz-imidazole-5-carboxyl-ate.

ABSTRACT: In the title compound, C(24)H(25)N(3)O(5), the benzimidazole and benzodioxole ring systems are each approximately planar [maximum deviations = 0.043?(1) and 0.036?(1)?Å, respectively]. Their mean planes form a dihedral angle of 42.85?(4)°. The pyrrolidine ring has an envelope conformation with one of the methyl-ene C atoms forming the flap. In the crystal, weak C-H?O hydrogen bonds link the mol-ecules into a three-dimensional network. The crystal packing is further stabillized by weak ?-? inter-actions between the benzene rings within the benzimidazole ring system [centroid-centroid distance = 3.7955?(7)?Å]. A weak C-H?? inter-action involving the benzodioxole ring is also present.

SUBMITTER: Yoon YK

PROVIDER: S-EPMC3275223 | biostudies-literature | 2012 Feb

REPOSITORIES: biostudies-literature

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Ethyl 2-(1,3-benzodioxol-5-yl)-1-[3-(2-oxopyrrolidin-1-yl)prop-yl]-1H-benz-imidazole-5-carboxyl-ate.

Yoon Yeong Keng YK Ali Mohamed Ashraf MA Wei Ang Chee AC Asik Safra Izuani Jama SI Razak Ibrahim Abdul IA

Acta crystallographica. Section E, Structure reports online 20120121 Pt 2

In the title compound, C(24)H(25)N(3)O(5), the benzimidazole and benzodioxole ring systems are each approximately planar [maximum deviations = 0.043 (1) and 0.036 (1) Å, respectively]. Their mean planes form a dihedral angle of 42.85 (4)°. The pyrrolidine ring has an envelope conformation with one of the methyl-ene C atoms forming the flap. In the crystal, weak C-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network. The crystal packing is further stabillized by weak π-π inter- ...[more]

PMID: 22347079

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Ethyl 2-(1,3-benzodioxol-5-yl)-1-[3-(1H-imidazol-1-yl)prop-yl]-1H-benzimidazole-5-carboxyl-ate.

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