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(E)-2-({2-[(E)-(Hy-droxy-imino)-meth-yl]phen-oxy}meth-yl)-3-o-tolyl-acrylonitrile.

ABSTRACT: In the title compound, C(18)H(16)N(2)O(2), the dihedral angle between the mean planes through the two benzene rings is 56.8?(6)°. The enoate group assumes an extended conformation. The hy-droxy-ethanimine group is essentially coplanar with the benzene ring, the largest deviation from the mean plane being 0.047?(1)?Å for the hy-droxy-imino O atom. In the crystal, the mol-ecules are linked into cyclic centrosymmetric dimers with R(2) (2)(6) motifs via O-H?N hydrogen bonds.

SUBMITTER: Govindan E

PROVIDER: S-EPMC3275232 | biostudies-literature | 2012 Feb

REPOSITORIES: biostudies-literature

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(E)-2-({2-[(E)-(Hy-droxy-imino)-meth-yl]phen-oxy}meth-yl)-3-o-tolyl-acrylonitrile.

Govindan E E Srinivasan J J Bakthadoss M M Subbiahpandi A A

Acta crystallographica. Section E, Structure reports online 20120121 Pt 2

In the title compound, C(18)H(16)N(2)O(2), the dihedral angle between the mean planes through the two benzene rings is 56.8 (6)°. The enoate group assumes an extended conformation. The hy-droxy-ethanimine group is essentially coplanar with the benzene ring, the largest deviation from the mean plane being 0.047 (1) Å for the hy-droxy-imino O atom. In the crystal, the mol-ecules are linked into cyclic centrosymmetric dimers with R(2) (2)(6) motifs via O-H⋯N hydrogen bonds. ...[more]

PMID: 22347088

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