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Dicyclo-hex-yl(4-isopropyl-phen-yl)phosphane selenide.

ABSTRACT: In the title compund, C(21)H(33)PSe, the Se=P bond is part of a distorted tetra-hedral environment on the P atom. Both cyclo-hexyl groups adopt chair conformations. A cone angle of 170° was calculated using an adaptation of the Tolman model. Inter-molecular C-H?Se and C-H?Cg contacts are observed (Cg is the centroid of the benzene ring).

SUBMITTER: Makhoba S

PROVIDER: S-EPMC3295440 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Dicyclo-hex-yl(4-isopropyl-phen-yl)phosphane selenide.

Makhoba Sizwe S Muller Alfred A Phasha Zanele Z

Acta crystallographica. Section E, Structure reports online 20120210 Pt 3

In the title compund, C(21)H(33)PSe, the Se=P bond is part of a distorted tetra-hedral environment on the P atom. Both cyclo-hexyl groups adopt chair conformations. A cone angle of 170° was calculated using an adaptation of the Tolman model. Inter-molecular C-H⋯Se and C-H⋯Cg contacts are observed (Cg is the centroid of the benzene ring). ...[more]

PMID: 22412551

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