Unknown

Dataset Information

0

2-Amino-3-(hy-droxy-meth-yl)pyridinium 2-benzoyl-benzoate monohydrate.


ABSTRACT: In the title hydrated salt, C(6)H(9)N(2)O(+)·C(14)H(9)O(3) (-)·H(2)O, the dihedral angle between the benzene rings of the 2-benzoyl-benzoate anion is 82.04 (14)°, while the angles between the aromatic ring of the pyridinium cation and each of the benzene rings of the anion are 4.42 (14) and 82.04 (14)°. In the crystal, mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds, generating a three-dimensional network with R(2) (2)(8), R(6) (6)(16) and R(4) (4)(6) motifs. The crystal packing is further stabilized by two π-π inter-actions, one between pyridinium rings, and another between the benzene benzoate and pyridinium rings of neighbouring mol-ecules, with centroid-to-centroid distances of 3.559 (2) and 3.606 (2) Å, respectively.

SUBMITTER: Odabasoglu HY 

PROVIDER: S-EPMC3295483 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

altmetric image

Publications

2-Amino-3-(hy-droxy-meth-yl)pyridinium 2-benzoyl-benzoate monohydrate.

Odabaşoğlu Hakkı Yasin HY   Büyükgüngör Orhan O   Avinç Osman Ozan OO   Odabaşoğlu Mustafa M  

Acta crystallographica. Section E, Structure reports online 20120217 Pt 3


In the title hydrated salt, C(6)H(9)N(2)O(+)·C(14)H(9)O(3) (-)·H(2)O, the dihedral angle between the benzene rings of the 2-benzoyl-benzoate anion is 82.04 (14)°, while the angles between the aromatic ring of the pyridinium cation and each of the benzene rings of the anion are 4.42 (14) and 82.04 (14)°. In the crystal, mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds, generating a three-dimensional network with R(2) (2)(8), R(6) (6)(16) and R(4) (4)(6) motifs. The crystal packing is furth  ...[more]

Similar Datasets

| S-EPMC3007529 | biostudies-literature
| S-EPMC3200843 | biostudies-literature
| S-EPMC2959924 | biostudies-literature
| S-EPMC3006953 | biostudies-literature
| S-EPMC3008107 | biostudies-literature
| S-EPMC3007284 | biostudies-literature
| S-EPMC3007449 | biostudies-literature
| S-EPMC3770390 | biostudies-literature
| S-EPMC3629648 | biostudies-literature
| S-EPMC3515224 | biostudies-literature