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1-(3,5-Dichloro-phen-yl)-3-(2-meth-oxy-phen-yl)triaz-1-ene.

ABSTRACT: The title mol-ecule, C(13)H(11)Cl(2)N(3)O, is almost planar and adopts a trans conformation with respect to the -N=N- bond; the dihedral angle between the rings is 3.47?(2)°. The N-N bond lengths indicate the presence of single- and double-bond characters and hence the -N=N-NH- moiety. In the crystal, inversion dimers linked by pairs of N-H?Cl hydrogen bonds occur, and C-H?? and ?-? stacking interactions are also observed.

SUBMITTER: Melardi MR

PROVIDER: S-EPMC3295495 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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1-(3,5-Dichloro-phen-yl)-3-(2-meth-oxy-phen-yl)triaz-1-ene.

Melardi Mohammad Reza MR Aghamohamadi Maryam M Attar Gharamaleki Jafar J Rofouei Mohammad Kazem MK Notash Behrouz B

Acta crystallographica. Section E, Structure reports online 20120217 Pt 3

The title mol-ecule, C(13)H(11)Cl(2)N(3)O, is almost planar and adopts a trans conformation with respect to the -N=N- bond; the dihedral angle between the rings is 3.47 (2)°. The N-N bond lengths indicate the presence of single- and double-bond characters and hence the -N=N-NH- moiety. In the crystal, inversion dimers linked by pairs of N-H⋯Cl hydrogen bonds occur, and C-H⋯π and π-π stacking interactions are also observed. ...[more]

PMID: 22412606

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