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Di-?-chlorido-bis-[(1,10-phenanthroline-?N,N')(trichloro-acetato-?O)copper(II)].

ABSTRACT: The title compound, [Cu(2)(C(2)Cl(3)O(2))(2)Cl(2)(C(12)H(8)N(2))(2)], features a centrosymmetric binuclear complex. The coordination geometry around the Cu(II) atom is square-pyramidal, comprising two N atoms from a symmetrically chelating 1,10-phenanthroline ligand, one O atom from a trichloro-acetate ligand and two Cl(-) anions. In addition, there is a weak intra-molecular Cu?O inter-action of 2.9403?(14)?Å involving the carbonyl O atom of the trichloro-acetate ligand. The central Cu(2)Cl(2) core takes the form of a rhombus, owing to the disparate Cu-Cl bond lengths. Mol-ecules are connected in the crystal structure by C-H?Cl and C-H?O inter-actions.

SUBMITTER: Shahverdizadeh GH

PROVIDER: S-EPMC3297214 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Di-μ-chlorido-bis-[(1,10-phenanthroline-κN,N')(trichloro-acetato-κO)copper(II)].

Shahverdizadeh Gholam Hossein GH Ng Seik Weng SW Tiekink Edward R T ER Mirtamizdoust Babak B

Acta crystallographica. Section E, Structure reports online 20120204 Pt 3

The title compound, [Cu(2)(C(2)Cl(3)O(2))(2)Cl(2)(C(12)H(8)N(2))(2)], features a centrosymmetric binuclear complex. The coordination geometry around the Cu(II) atom is square-pyramidal, comprising two N atoms from a symmetrically chelating 1,10-phenanthroline ligand, one O atom from a trichloro-acetate ligand and two Cl(-) anions. In addition, there is a weak intra-molecular Cu⋯O inter-action of 2.9403 (14) Å involving the carbonyl O atom of the trichloro-acetate ligand. The central Cu(2)Cl(2) c ...[more]

PMID: 22412404

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