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Catena-Poly[[bis-(1-methyl-1H-imidazole-?N)zinc]-?-3-nitro-phthalato-?O:O].

ABSTRACT: In the title complex, [Zn(C(8)H(3)NO(6))(C(4)H(6)N(2))(2)](n), the carboxyl-ate groups of the 3-nitro-phthalate dianion ligand coordinate the Zn(II) ion in a bis-monodentate mode. The Zn(II) ion shows distorted tetra-hedral coordination as it is bonded to two O atoms from the carboxyl-ate groups of symmetry-related 3-nitro-phthalate anions and two N atoms of two independent 1-methyl-imidazole mol-ecules. The bridging 3-nitro-phthalate ligand allows the formation of one-dimensional chains in the c direction. The crystal structure is further stabilized by weak inter-molecular C-H?O hydrogen bonds.

SUBMITTER: Zhang XJ 

PROVIDER: S-EPMC3297226 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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catena-Poly[[bis-(1-methyl-1H-imidazole-κN)zinc]-μ-3-nitro-phthalato-κO:O].

Zhang Xi-Juan XJ   Guo Ming-Lin ML  

Acta crystallographica. Section E, Structure reports online 20120210 Pt 3

In the title complex, [Zn(C(8)H(3)NO(6))(C(4)H(6)N(2))(2)](n), the carboxyl-ate groups of the 3-nitro-phthalate dianion ligand coordinate the Zn(II) ion in a bis-monodentate mode. The Zn(II) ion shows distorted tetra-hedral coordination as it is bonded to two O atoms from the carboxyl-ate groups of symmetry-related 3-nitro-phthalate anions and two N atoms of two independent 1-methyl-imidazole mol-ecules. The bridging 3-nitro-phthalate ligand allows the formation of one-dimensional chains in the  ...[more]

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