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Tetra-aqua-tetra-kis-(4,4'-bipyridine dioxide-?O)terbium(III) octa-cyanidotungstate(V).

ABSTRACT: In the title compound, [Tb(C(10)H(8)N(2)O(2))(4)(H(2)O)(4)][W(CN)(8)], both metal atoms are eight-coordinated. The Tb(III) ion displays a dodeca-hedral geometry, while the W(v) ion exhibits a distorted square-anti-prismatic geometry. The Tb atoms are located on a special position of site symmetry -4, whereas the W atoms are located on a twofold rotation axis. The cations are linked by O-H?O hydrogen bonds. The title compound is isotypic with the corresponding and previously described Mo compound [Qian & Yuan (2011 ?). Acta Cryst. E67, m845].

SUBMITTER: Shi YS 

PROVIDER: S-EPMC3297244 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Tetra-aqua-tetra-kis-(4,4'-bipyridine dioxide-κO)terbium(III) octa-cyanidotungstate(V).

Shi Yu-Sheng YS   Ran Mao-Qian MQ   Chen Ying-Ying YY   Yuan Ai-Hua AH  

Acta crystallographica. Section E, Structure reports online 20120210 Pt 3

In the title compound, [Tb(C(10)H(8)N(2)O(2))(4)(H(2)O)(4)][W(CN)(8)], both metal atoms are eight-coordinated. The Tb(III) ion displays a dodeca-hedral geometry, while the W(v) ion exhibits a distorted square-anti-prismatic geometry. The Tb atoms are located on a special position of site symmetry -4, whereas the W atoms are located on a twofold rotation axis. The cations are linked by O-H⋯O hydrogen bonds. The title compound is isotypic with the corresponding and previously described Mo compound  ...[more]

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