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Ethyl 2-amino-4,6-bis-(4-fluoro-phen-yl)cyclo-hexa-1,3-diene-1-carboxyl-ate.

ABSTRACT: In the title compound, C(21)H(19)F(2)NO(2), the cyclo-hexa-1,3-diene ring is in a distorted envelope conformation. The dihedral angles between the mean planes of the diene moiety and the two fluoro-phenyl rings are 42.8?(2) and 75.0?(5)°. The two fluoro-phenyl rings are inclined to one another by 87.0?(3)°. In the crystal, intra-molecular N-H?O hydrogen bonds and weak N-H?O and N-H?F inter-molecular inter-actions are observed forming an infinite two-dimensional network along [011].

SUBMITTER: Jasinski JP

PROVIDER: S-EPMC3297311 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Ethyl 2-amino-4,6-bis-(4-fluoro-phen-yl)cyclo-hexa-1,3-diene-1-carboxyl-ate.

Jasinski Jerry P JP Golen James A JA Samshuddin S S Samshuddin S S Narayana B B Yathirajan H S HS

Acta crystallographica. Section E, Structure reports online 20120204 Pt 3

In the title compound, C(21)H(19)F(2)NO(2), the cyclo-hexa-1,3-diene ring is in a distorted envelope conformation. The dihedral angles between the mean planes of the diene moiety and the two fluoro-phenyl rings are 42.8 (2) and 75.0 (5)°. The two fluoro-phenyl rings are inclined to one another by 87.0 (3)°. In the crystal, intra-molecular N-H⋯O hydrogen bonds and weak N-H⋯O and N-H⋯F inter-molecular inter-actions are observed forming an infinite two-dimensional network along [011]. ...[more]

PMID: 22412501

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