Browse
Submit Data
Databases
API
Help

Dataset Information

18 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(E)-3-Methyl-N'-(4-nitro-benzyl-idene)benzohydrazide methanol monosolvate.

ABSTRACT: The title hydrazone compound, C(15)H(13)N(3)O(3)·CH(3)OH, crystallized as a methanol solvate. The hydrazone mol-ecule has an E configuration about the C=N bond and is almost planar, with a dihedral angle between the benzene rings of 5.3?(3)°. In the crystal, the hydrazone mol-ecules are linked via the methanol solvent mol-ecule through N-H?O and O-H?O hydrogen bonds, so forming chains propagating along the a-axis direction.

SUBMITTER: Tang CB

PROVIDER: S-EPMC3297325 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(E)-3-Methyl-N'-(4-nitro-benzyl-idene)benzohydrazide methanol monosolvate.

Tang Chun-Bao CB

Acta crystallographica. Section E, Structure reports online 20120204 Pt 3

The title hydrazone compound, C(15)H(13)N(3)O(3)·CH(3)OH, crystallized as a methanol solvate. The hydrazone mol-ecule has an E configuration about the C=N bond and is almost planar, with a dihedral angle between the benzene rings of 5.3 (3)°. In the crystal, the hydrazone mol-ecules are linked via the methanol solvent mol-ecule through N-H⋯O and O-H⋯O hydrogen bonds, so forming chains propagating along the a-axis direction. ...[more]

PMID: 22412515

Similar Datasets

4-Dimethyl-amino-N'-(4-nitro-benzyl-idene)benzohydrazide methanol monosolvate.

Project description:In the title compound, C(16)H(16)N(4)O(3)·CH(3)OH, the aromatic rings form a dihedral angle of 0.4?(2)°. The nitro group is twisted from the attached benzene ring by 7.5?(2)°. In the crystal, N-H?O and O-H?O hydrogen bonds link alternating hydrazone and methanol mol-ecules into chains in [100]. The crystal packing exhibits ?-? inter-actions between aromatic rings from neighbouring chains [centroid-centroid distances = 3.734?(3) and 3.903?(3)?Å].

| S-EPMC3470190 | biostudies-literature

(E)-4-Meth-oxy-N'-(4-nitro-benzyl-idene)benzohydrazide methanol monosolvate.

Project description:The hydrazone mol-ecule of the title compound, C(15)H(13)N(3)O(4)·CH(4)O, is nearly planar, with a dihedral angle between the two benzene rings of 1.2?(4)°. The mol-ecule exists in a trans configuration with respect to the central methyl-idene unit. In the crystal, the benzohydrazide and methanol mol-ecules are linked through inter-molecular O-H?O, O-H?N and N-H?O hydrogen bonds, forming chains along the a axis.

| S-EPMC3011623 | biostudies-literature

N'-(5-Bromo-2-hy-droxy-benzyl-idene)-4-nitro-benzohydrazide methanol monosolvate.

Project description:In the title compound, C(14)H(10)BrN(3)O(4)·CH(4)O, the benzohydrazide mol-ecule is nearly planar [maximum deviation = 0.110?(2)?Å]. The mean planes of the two benzene rings make a dihedral angle of 8.4?(3)°. In the benzohydrazide mol-ecule, there is an intra-molecular O-H?N hydrogen bond and the NH group is hydrogen bonded to the methanol solvent mol-ecule. In the crystal, inter-molecular O-H?O hydrogen bonds involving the methanol solvent mol-ecule link the benzohydrazide mol-ecules to form chains which propagate along the a axis.

| S-EPMC3213628 | biostudies-literature

N'-(3,5-Dibromo-2-hy-droxy-benzyl-idene)-4-nitro-benzohydrazide methanol monosolvate.

Project description:The title compound, C(14)H(9)Br(2)N(3)O(4)·CH(4)O, was obtained as the product of the reaction of 3,5-dibromo-salicyl-aldehyde with 4-nitro-benzohydrazide in methanol. The benzohydrazide mol-ecule is nearly planar, with a maximum deviation of 0.126?(2)?Å. The mean planes of the two benzene rings make a dihedral angle of 9.3?(3)°. Intra-molecular O-H?N and O-H?Br inter-actions are observed in the benzohydrazide mol-ecule. In the crystal, pairs of adjacent benzohydrazide mol-ecules are linked by two methanol mol-ecules through inter-molecular O-H?O and N-H?O hydrogen bonds, forming a dimer.

| S-EPMC3200651 | biostudies-literature

(E)-N'-[4-(Dimethyl-amino)-benzyl-idene]-4-methyl-benzohydrazide methanol monosolvate.

Project description:In the title compound, C(17)H(19)N(3)O·CH(3)OH, the hydrazone mol-ecule exists in a trans geometry with respect to the methyl-idene unit and the dihedral angle between the two substituted benzene rings is 42.6?(2)°. In the crystal, the components are linked through N-H?O and O-H?O hydrogen bonds, forming [100] chains of alternating hydrazone and methanol mol-ecules.

| S-EPMC3213579 | biostudies-literature

4-Chloro-N'-(4-meth-oxy-benzyl-idene)benzohydrazide methanol monosolvate.

Project description:The title compound, C(15)H(13)ClN(2)O(2)·CH(4)O, consists of a 4-chloro-N'-(4-meth-oxy-benzyl-idene)benzohydrazide (CMB) mol-ecule and a methanol mol-ecule of crystallization. It was obtained by the condensation of 4-meth-oxy-benzaldehyde with 4-chloro-benzohydrazide. In the CMB mol-ecule, the dihedral angle between the two benzene rings is 50.1?(3)°. The methanol mol-ecule is linked to the CMB mol-ecule through O-H?O and O-H?N hydrogen bonds. In the crystal, CMB mol-ecules are linked through inter-molecular N-H?O hydrogen bonds, involving the methanol mol-ecule, forming chains propagating along [010].

| S-EPMC3009357 | biostudies-literature

(E)-4-Methyl-N'-(3-nitro-benzyl-idene)benzohydrazide.

Project description:In the title compound, C(15)H(13)N(3)O(3), the dihedral angle between the benzene rings is 1.01?(3)° and that between the nitro group and its attached ring is 5.99?(15)°. In the crystal, mol-ecules are linked by N-H?O hydrogen bonds generating C(4) chains along [010].

| S-EPMC3379220 | biostudies-literature

N'-(3,4-Dimeth-oxy-benzyl-idene)-3,5-dihy-droxy-benzohydrazide methanol monosolvate.

Project description:In the title compound, C(16)H(16)N(2)O(5)·CH(4)O, the two benzene rings in the Schiff base mol-ecule form a dihedral angle of 17.1?(1)°. In the crystal, inter-molecular O-H?O hydrogen bonds link the components into corrugated sheets parallel to the (101) plane.

| S-EPMC3213620 | biostudies-literature

N'-[(E)-4-Benz-yloxy-2-hy-droxy-benzyl-idene]-4-nitro-benzohydrazide di-methyl-formamide monosolvate.

Project description:The title compound, C21H17N3O5·C3H7NO, exists in an E conformation with respect to the azomethine double bond of the hydrazide mol-ecule. This mol-ecule contains an intra-molecular O-H?N hydrogen bond, while an inter-molecular N-H?O hydrogen bond links the hydrazide to the formamide mol-ecule of solvation. Nonclassical C-H?O inter-molecular hydrogen bonds build up a supra-molecular architecture, together with two C-H?? inter-actions and a weak ?-? inter-action, with a centroid-centroid distance of 3.650?(13)?Å.

| S-EPMC3770421 | biostudies-literature

N'-[(Z)-4-Methyl-benzyl-idene]-4-nitro-benzohydrazide monohydrate.

Project description:In the title compound, C(15)H(13)N(3)O(3)·H(2)O, the two benzene rings form a dihedral angle of 2.03?(2)°. In the crystal structure, adjacent hydrazide mol-ecules are linked into dimers by water mol-ecules; these dimers are then stacked along the b axis. Inter-molecular O-H?O, O-H?N and C-H?O hydrogen bonds and a ?-? stacking inter-action between the nitro-benzene and tolyl rings with a centroid-centroid distance of 3.8208?(3)?Å are observed. There is also a short O?N contact [2.6824?(7)?Å].

| S-EPMC2960119 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data