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Ethyl N-(2-benzoyl-4-chloro-phen-yl)-ethane-carboximidate.

ABSTRACT: In the title compound, C(17)H(16)ClNO(2), the N=C-O-C-C fragment is planar within 0.029?(1)?Å, and makes dihedral angles of 66.71?(8) and 59.61?(8)° with the planes of the chloro-phenyl and benzoyl rings, respectively. The carbonyl C=O bond is not coplanar with either of the aromatic rings; it makes angles of 42.5 and 23.5° with the normals to the ring planes. In the crystal, very weak C-H?O, C-H?Cl, C-H?? and ?-? [inter-planar distance = 3.53?(1)?Å] inter-actions are observed.

SUBMITTER: Sumathi HP

PROVIDER: S-EPMC3297957 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Ethyl N-(2-benzoyl-4-chloro-phen-yl)-ethane-carboximidate.

Sumathi H P HP Dayananda A S AS Dutkiewicz Grzegorz G Yathirajan H S HS Kubicki Maciej M

Acta crystallographica. Section E, Structure reports online 20120229 Pt 3

In the title compound, C(17)H(16)ClNO(2), the N=C-O-C-C fragment is planar within 0.029 (1) Å, and makes dihedral angles of 66.71 (8) and 59.61 (8)° with the planes of the chloro-phenyl and benzoyl rings, respectively. The carbonyl C=O bond is not coplanar with either of the aromatic rings; it makes angles of 42.5 and 23.5° with the normals to the ring planes. In the crystal, very weak C-H⋯O, C-H⋯Cl, C-H⋯π and π-π [inter-planar distance = 3.53 (1) Å] inter-actions are observed. ...[more]

PMID: 22412760

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