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1-(Ferrocen-1-ylmeth-yl)-3-methyl-imidazol-3-ium hexa-fluorido-phosphate.

ABSTRACT: The crystal structure of the title compound, [Fe(C(5)H(5))(C(10)H(12)N(2))]PF(6), consists of a ferrocene-1-methyl-(3-methyl-imidazolium) cation and a hexa-fluorido-phosphate anion. The ferrocenyl rings are skewed by 6.7?(4)° from the ideal eclipsed conformation. The inter-planar angle between the plane of the substituted cyclo-penta-dienyl ring and that of the imidazole ring is 89.9?(4)°. The crystal packing is stabilized by C-H?F hydrogen bonds.

SUBMITTER: Nyamori VO

PROVIDER: S-EPMC3343779 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature

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1-(Ferrocen-1-ylmeth-yl)-3-methyl-imidazol-3-ium hexa-fluorido-phosphate.

Nyamori Vincent O VO Zulu Siphesihle M SM Omondi Bernard B

Acta crystallographica. Section E, Structure reports online 20120303 Pt 4

The crystal structure of the title compound, [Fe(C(5)H(5))(C(10)H(12)N(2))]PF(6), consists of a ferrocene-1-methyl-(3-methyl-imidazolium) cation and a hexa-fluorido-phosphate anion. The ferrocenyl rings are skewed by 6.7 (4)° from the ideal eclipsed conformation. The inter-planar angle between the plane of the substituted cyclo-penta-dienyl ring and that of the imidazole ring is 89.9 (4)°. The crystal packing is stabilized by C-H⋯F hydrogen bonds. ...[more]

PMID: 22589753

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