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2-[(E)-(1,10-Phenanthrolin-5-yl)imino-meth-yl]phenol methanol monosolvate.

ABSTRACT: In the title multi-donor Schiff base compound, C(19)H(13)N(3)O·CH(3)OH, the dihedral angle between the mean planes of the phenanthroline and phenol rings is 59.3?(1)°. The Schiff base mol-ecule is linked to the solvent mol-ecule by an O-H?O hydrogen bond. In the crystal, the components are linked by O-H?N hydrogen bonds, weak O-H?N inter-actions and ?-? stacking inter-actions [centroid-centroid distances = 3.701?(1) and 3.656?(1)?Å].

SUBMITTER: Ozturk Yildirim S 

PROVIDER: S-EPMC3344113 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature

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2-[(E)-(1,10-Phenanthrolin-5-yl)imino-meth-yl]phenol methanol monosolvate.

Oztürk Yíldírím Sema S   Demirhan Nebahat N   Elmalí Fikriye F   Butcher Ray J RJ  

Acta crystallographica. Section E, Structure reports online 20120324 Pt 4

In the title multi-donor Schiff base compound, C(19)H(13)N(3)O·CH(3)OH, the dihedral angle between the mean planes of the phenanthroline and phenol rings is 59.3 (1)°. The Schiff base mol-ecule is linked to the solvent mol-ecule by an O-H⋯O hydrogen bond. In the crystal, the components are linked by O-H⋯N hydrogen bonds, weak O-H⋯N inter-actions and π-π stacking inter-actions [centroid-centroid distances = 3.701 (1) and 3.656 (1) Å]. ...[more]

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