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2,11-Dibromo-5,8-dibut-yl[4]helicene.

ABSTRACT: A racemic mixture of the title compound, C(26)H(26)Br(2), a brominated [4]helicene, crystallizes, forming columns of stacked mol-ecules. There are two crystallographically unique mol-ecules in the asymmetric unit, both with the same helical handedness. As is typical with helicene congeners, the unique mol-ecules show short inter-atomic contacts between H atoms at the fjord region, with H?H distances of 1.87 and 1.94?Å. Mol-ecules with the same helical handedness segregate in the crystal packing, forming homochiral columns. The stacked mol-ecules are piled in a column with alternate orientations. The shortest C?C distance in the stacked mol-ecules is 3.306?(4)?Å.

SUBMITTER: Isobe H

PROVIDER: S-EPMC3344169 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature

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2,11-Dibromo-5,8-dibut-yl[4]helicene.

Isobe Hiroyuki H Matsuno Taisuke T Hitosugi Shunpei S Nakanishi Waka W

Acta crystallographica. Section E, Structure reports online 20120331 Pt 4

A racemic mixture of the title compound, C(26)H(26)Br(2), a brominated [4]helicene, crystallizes, forming columns of stacked mol-ecules. There are two crystallographically unique mol-ecules in the asymmetric unit, both with the same helical handedness. As is typical with helicene congeners, the unique mol-ecules show short inter-atomic contacts between H atoms at the fjord region, with H⋯H distances of 1.87 and 1.94 Å. Mol-ecules with the same helical handedness segregate in the crystal packing, ...[more]

PMID: 22606172

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