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Cis-Tetra-chloridobis(1H-imidazole-?N(3))platinum(IV).

ABSTRACT: In the title complex, cis-[PtCl(4)(C(3)H(4)N(2))(2)], the Pt(IV) ion lies on a twofold rotation axis and is coordinated in a slightly distorted octa-hedral geometry. The dihedral angle between the imidazole rings is 69.9?(2)°. In the crystal, mol-ecules are linked by N-H?Cl hydrogen bonds, forming a three-dimensional network.

SUBMITTER: Bokach NA

PROVIDER: S-EPMC3344304 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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cis-Tetra-chloridobis(1H-imidazole-κN(3))platinum(IV).

Bokach Nadezhda A NA Kukushkin Vadim Yu VY Izotova Yulia A YA Usenko Natalia I NI Haukka Matti M

Acta crystallographica. Section E, Structure reports online 20120404 Pt 5

In the title complex, cis-[PtCl(4)(C(3)H(4)N(2))(2)], the Pt(IV) ion lies on a twofold rotation axis and is coordinated in a slightly distorted octa-hedral geometry. The dihedral angle between the imidazole rings is 69.9 (2)°. In the crystal, mol-ecules are linked by N-H⋯Cl hydrogen bonds, forming a three-dimensional network. ...[more]

PMID: 22590070

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