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Tetra-aqua-bis-[3-(pyridin-4-yl)benzoato-?N]manganese(II).

ABSTRACT: In the title compound, [Mn(C(12)H(8)NO(2))(2)(H(2)O)(4)], the Mn(2+) ion lies on a twofold rotation axis and has a distorted N(2)O(4) octa-hedral coordination geometry formed by four water O atoms in the equatorial plane and two apical pyridyl N atoms. A three-dimensional network is formed in the crystal structure by multiple O-H?O hydrogen bonds between the coordin-ating water molecules and the free carboxylate groups.

SUBMITTER: Gao RQ

PROVIDER: S-EPMC3344315 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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Tetra-aqua-bis-[3-(pyridin-4-yl)benzoato-κN]manganese(II).

Gao Ru-Qin RQ Li Guo-Ting GT

Acta crystallographica. Section E, Structure reports online 20120413 Pt 5

In the title compound, [Mn(C(12)H(8)NO(2))(2)(H(2)O)(4)], the Mn(2+) ion lies on a twofold rotation axis and has a distorted N(2)O(4) octa-hedral coordination geometry formed by four water O atoms in the equatorial plane and two apical pyridyl N atoms. A three-dimensional network is formed in the crystal structure by multiple O-H⋯O hydrogen bonds between the coordin-ating water molecules and the free carboxylate groups. ...[more]

PMID: 22590081

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