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Cis-[1,4-Bis(diphenyl-phosphan-yl)butane-?(2)P,P']dichlorido(cyclo-hexane-1,2-diamine-?(2)N,N')ruthenium(II) dichloro-methane monosolvate.

ABSTRACT: In the title compound, [RuCl(2)(C(6)H(14)N(2))(C(28)H(28)P(2))]·CH(2)Cl(2), the Ru(II) ion is coordinated in a slightly distorted octa-hedral environment, formed by two cis-oriented chloride ligands, two cis P atoms of a 1,4-bis-(diphenyl-phosphan-yl)butane ligand and two cis-chelating N atoms of a bidentate cyclo-hexane-1,2-diamine ligand. In the crystal, pairs of mol-ecules form inversion dimers via N-H?Cl hydrogen bonds. In addition, intra-molecular N-H?Cl and weak C-H?Cl, C-H?N, N-H?? and C-H?? hydrogen bonds are observed. One of the Cl atoms of the solvent mol-ecule is disordered over two sites with refined occupancies of 0.62?(1) and 0.38?(1).

SUBMITTER: Warad I

PROVIDER: S-EPMC3344316 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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cis-[1,4-Bis(diphenyl-phosphan-yl)butane-κ(2)P,P']dichlorido(cyclo-hexane-1,2-diamine-κ(2)N,N')ruthenium(II) dichloro-methane monosolvate.

Warad Ismail I

Acta crystallographica. Section E, Structure reports online 20120413 Pt 5

In the title compound, [RuCl(2)(C(6)H(14)N(2))(C(28)H(28)P(2))]·CH(2)Cl(2), the Ru(II) ion is coordinated in a slightly distorted octa-hedral environment, formed by two cis-oriented chloride ligands, two cis P atoms of a 1,4-bis-(diphenyl-phosphan-yl)butane ligand and two cis-chelating N atoms of a bidentate cyclo-hexane-1,2-diamine ligand. In the crystal, pairs of mol-ecules form inversion dimers via N-H⋯Cl hydrogen bonds. In addition, intra-molecular N-H⋯Cl and weak C-H⋯Cl, C-H⋯N, N-H⋯π and C- ...[more]

PMID: 22590082

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