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Tetra-kis[?(3)-4-nitro-N-(5-phenyl-1,3,4-oxadiazol-2-yl)benzamidato]tetra-kis-[methano-lsodium(I)].

ABSTRACT: In the title compound, [Na(4)(C(15)H(9)N(4)O(4))(4)(CH(3)OH)(4)], the N(3)O(3) environment around the Na(+) ion is distorted octa-hedral. In the unit cell, four Na(+) ions are bridged by four Schiff base anions, leading to a tetra-nuclear complex with -4 symmetry. O-H?N hydrogen bonds between the methanol mol-ecule and the Schiff base anion stabilize the structural set-up.

SUBMITTER: Yin GJ

PROVIDER: S-EPMC3344320 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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Tetra-kis[μ(3)-4-nitro-N-(5-phenyl-1,3,4-oxadiazol-2-yl)benzamidato]tetra-kis-[methano-lsodium(I)].

Yin Guo-Jie GJ Zhang Qing Q Li Dong D

Acta crystallographica. Section E, Structure reports online 20120413 Pt 5

In the title compound, [Na(4)(C(15)H(9)N(4)O(4))(4)(CH(3)OH)(4)], the N(3)O(3) environment around the Na(+) ion is distorted octa-hedral. In the unit cell, four Na(+) ions are bridged by four Schiff base anions, leading to a tetra-nuclear complex with -4 symmetry. O-H⋯N hydrogen bonds between the methanol mol-ecule and the Schiff base anion stabilize the structural set-up. ...[more]

PMID: 22590086

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