Unknown

Dataset Information

0

Catena-Poly[[aqua-(2-iodo-benzoato-?O)cobalt(II)]-?-aqua-?-2-iodo-benzoato-?(2)O:O'].

ABSTRACT: The asymmetric unit of the polymeric title compound, [Co(C(7)H(4)IO(2))(2)(H(2)O)(2)](n), contains one Co(II) cation, two iodo-benzoate anions and two water mol-ecules. One iodo-benzoate anion and one water mol-ecule bridge adjacent Co cations, forming a polymeric chain running along the a axis, while the other iodo-benzoate anion and water mol-ecule coordinate in a monodentate manner to the Co(II) cation, completing the slightly distorted octa-hedral geometry. In the two independent anionic ligands, the carboxyl-ate groups are twisted away from the attached benzene rings by 51.38?(18) and 39.89?(11)°, and the two benzene rings are nearly perpendicular to each other with a dihedral angle of 86.09?(10)°. Intra-molecular O-H?O hydrogen bonds between coordinating water mol-ecules and adjacent carboxyl-ate O atoms help to stabilize the mol-ecular structure. In the crystal, weak C-H?O hydrogen bonds link the polymeric chains into a three-dimentional supra-molecular network.

SUBMITTER: Ayd?n O 

PROVIDER: S-EPMC3344342 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[aqua-(2-iodo-benzoato-κO)cobalt(II)]-μ-aqua-μ-2-iodo-benzoato-κ(2)O:O'].

Aydın Omür O   Caylak Delibaş Nagihan N   Necefoğlu Hacali H   Hökelek Tuncer T  

Acta crystallographica. Section E, Structure reports online 20120418 Pt 5

The asymmetric unit of the polymeric title compound, [Co(C(7)H(4)IO(2))(2)(H(2)O)(2)](n), contains one Co(II) cation, two iodo-benzoate anions and two water mol-ecules. One iodo-benzoate anion and one water mol-ecule bridge adjacent Co cations, forming a polymeric chain running along the a axis, while the other iodo-benzoate anion and water mol-ecule coordinate in a monodentate manner to the Co(II) cation, completing the slightly distorted octa-hedral geometry. In the two independent anionic lig  ...[more]

Similar Datasets

Unknown Crystal structure of catena-poly[[[di-aqua-bis-(2,4,6-tri-methyl-benzoato-κO)cobalt(II)]-μ-aqua-κ2O:O] dihydrate].
| S-EPMC5418789 | biostudies-literature
Unknown catena-Poly[[tetra-aqua-cobalt(II)]-?-2,2'-dihydroxy-5,5'-diazenediyldibenzoato].
| S-EPMC2960221 | biostudies-literature
Unknown catena-Poly[[diaqua-cobalt(II)]-bis-(?-4-fluoro-benzoato-?O:O')].
| S-EPMC2977626 | biostudies-literature
Unknown catena-Poly[[aqua-(2,2'-bipyridyl)cobalt(II)]-μ-5-nitro-isophthalato].
| S-EPMC2960127 | biostudies-literature
Unknown catena-Poly[[di-?-aqua-bis[aqua-cobalt(II)]]-bis(?(3)-1H-benzimidazole-5,6-dicarboxylato].
| S-EPMC2968675 | biostudies-literature
Unknown catena-Poly[[[diaqua-bis[4-(diethyl-amino)benzoato-?O]manganese(II)]-?-aqua] dihydrate].
| S-EPMC2969307 | biostudies-literature
Unknown catena-Poly[[aqua-(3-methyl-benzoato-?O,O')lead(II)]-?-3-methyl-benzoato-?O:O,O':O'].
| S-EPMC2969469 | biostudies-literature
Unknown catena-Poly[[aqua-(1,10-phenanthroline)cobalt(II)]-?-4,4'-(propane-1,3-diyldi-oxy)dibenzoato].
| S-EPMC2970340 | biostudies-literature
Unknown catena-Poly[[aqua-{4-[N'-(2,4-dioxo-3-pentyl-idene)-hydrazino]-benzoato}-copper(II)]-?-acetato].
| S-EPMC2961769 | biostudies-literature
Unknown catena-Poly[[aqua-cadmium(II)]-bis-(?(2)-4-chloro-benzoato)].
| S-EPMC2984089 | biostudies-other