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Poly[diaqua-bis-{?-5-[4-(1H-imidazol-1-ylmethyl)phen-yl]tetra-zolato}copper(II)].

ABSTRACT: In the title compound, [Cu(C(11)H(9)N(6))(2)(H(2)O)(2)](n), the Cu(II) atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmethyl)phen-yl]tetra-zolate ligands and two water mol-ecules in a distorted octa-hedral geometry. The ligands bridge the Cu(II) atoms, leading to the formation of a two-dimensional network parallel to (100). The structure is further stabilized by O-H?N hydrogen bonds within the network.

SUBMITTER: Li Y

PROVIDER: S-EPMC3344355 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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Poly[diaqua-bis-{μ-5-[4-(1H-imidazol-1-ylmethyl)phen-yl]tetra-zolato}copper(II)].

Li Yuan Y Chen Ruizhan R

Acta crystallographica. Section E, Structure reports online 20120418 Pt 5

In the title compound, [Cu(C(11)H(9)N(6))(2)(H(2)O)(2)](n), the Cu(II) atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmethyl)phen-yl]tetra-zolate ligands and two water mol-ecules in a distorted octa-hedral geometry. The ligands bridge the Cu(II) atoms, leading to the formation of a two-dimensional network parallel to (100). The structure is further stabilized by O-H⋯N hydrogen bonds within the network. ...[more]

PMID: 22590121

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trans-Diaqua-bis[5-(1H-imidazol-4-yl-κN)-1H-tetra-zolato-κN]zinc(II).

Project description:In the title complex, [Zn(C(4)H(3)N(6))(2)(H(2)O)(2)], the metal centre lies on an inversion centre and displays a distorted octa-hedral ZnN(4)O(2) coordination geometry. The organic ligand is not planar; the dihedral angle between the imidazole and tetra-zole rings is 8.39 (9)°. An extended network of inter-molecular N-H⋯N and O-H⋯N hydrogen bonds stabilizes the crystal structure.

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Poly[bis-(μ(2)-5-{4-[(1H-imidazol-1-yl)meth-yl]phen-yl}tetra-zolato)zinc].

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catena-Poly[(trans-diaqua-cadmium)-bis-{?-5-[4-(1H-imidazol-1-yl)phen-yl]tetra-zol-1-ido}].

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catena-Poly[[[diaqua-copper(II)]-bis-[?-1,5-bis-(1H-imidazol-1-yl)pentane-?(2) N (3):N (3')]] naphthalene-1,5-disulfonate].

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| S-EPMC2961981 | biostudies-literature

Diaqua-bis[5-(2-pyrid-yl)tetra-zolato-κN,N]iron(II).

Project description:The title complex, [Fe(C(6)H(4)N(5))(2)(H(2)O)(2)], was synthesized by the reaction of ferrous sulfate with 5-(2-pyrid-yl)-2H-tetra-zole (HL). The Fe(II) atom, located on a crystallographic center of inversion, is coordinated by four N-atom donors from two planar trans-related deprotonated L ligands and two O atoms from two axial water mol-ecules in a distorted octa-hedral geometry. The Fe(II) mononuclear units are further connected by inter-molecular O-H⋯N and C-H⋯O hydrogen-bonding inter-actions, forming a three-dimensional framework.

| S-EPMC2968821 | biostudies-literature

Diaqua-bis[5-(2-pyridylmeth-yl)tetra-zolato-κN,N]manganese(II).

Project description:The title complex, [Mn(C(7)H(6)N(5))(2)(H(2)O)(2)], was obtained by the in situ hydro-thermal reaction of MnCl(2) with 2-(2-pyrid-yl)acetonitrile in the presence of NaN(3). The Mn(II) atom, which is located on an inversion centre, has a distorted octa-hedral coordination geometry formed by two water mol-ecules and two chelating ligands. Inter-molecular hydrogen bonds and π-π inter-actions (3.452 Å) stabilize the crystal structure and lead to the formation of a three-dimensional network.

| S-EPMC2961924 | biostudies-literature

catena-Poly[[[diaqua-manganese(II)]-bis-[μ-1,3-bis-(1H-imidazol-1-ylmeth-yl)benzene-κN:N]] dinitrate].

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