Unknown

Dataset Information

0

Catena-Poly[[(2-amino-1,3-benzothia-zole-6-carboxyl-ato-?(2)O,O')(2,2'-bipyridyl-?(2)N,N')cadmium]-?-2-amino-1,3-benzothia-zole-6-carboxyl-ato-?(3)N(1):O,O'].

ABSTRACT: In the title coordination polymer, [Cd(C(8)H(5)N(2)O(2)S)(2)(C(10)H(8)N(2))](n), the Cd(II) ion is coordinated by a bidentate 2,2-bipyridyl ligand, two O,O'-chelating 2-amino-1,3-benzothia-zole-6-carboxyl-ate (ABTC) ligands and one N-bonded ABTC ligand. The resulting CdN(3)O(4) coordination polyhedron approximates to a very distorted penta-gonal bipramid with one O and one N atom in axial positions. One of the ABTC ligands is bridging to an adjacent metal atom, generating an infinite chain propagating in [100]. A three-dimensional network is constructed from N-H?O and N-H?N hydrogen bonds and aromatic ?-? stacking inter-actions [centroid-centroid separations = 3.641?(2) and 3.682?(3)?Å].

SUBMITTER: Gao D 

PROVIDER: S-EPMC3344366 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[(2-amino-1,3-benzothia-zole-6-carboxyl-ato-κ(2)O,O')(2,2'-bipyridyl-κ(2)N,N')cadmium]-μ-2-amino-1,3-benzothia-zole-6-carboxyl-ato-κ(3)N(1):O,O'].

Gao Dan D   Fang Xin X   Zhang Ke-Ke KK   Cai Li-Mao LM   Wang Jun-Dong JD  

Acta crystallographica. Section E, Structure reports online 20120421 Pt 5

In the title coordination polymer, [Cd(C(8)H(5)N(2)O(2)S)(2)(C(10)H(8)N(2))](n), the Cd(II) ion is coordinated by a bidentate 2,2-bipyridyl ligand, two O,O'-chelating 2-amino-1,3-benzothia-zole-6-carboxyl-ate (ABTC) ligands and one N-bonded ABTC ligand. The resulting CdN(3)O(4) coordination polyhedron approximates to a very distorted penta-gonal bipramid with one O and one N atom in axial positions. One of the ABTC ligands is bridging to an adjacent metal atom, generating an infinite chain propa  ...[more]

Similar Datasets

Unknown catena-Poly[lead(II)-bis-(μ-2-amino-1,3-benzothia-zole-6-carboxyl-ato)].
| S-EPMC3011691 | biostudies-literature
Unknown 2,2'-Hexamethyl-enedi-1,3-benzothia-zole.
| S-EPMC2968253 | biostudies-literature
Unknown 2,2'-(Sulfanediyldimethyl-ene)bis-(1,3-benzothia-zole).
| S-EPMC3052028 | biostudies-literature
Unknown Ethyl 2-(tert-butoxy-carbonyl-amino)-1,3-benzothia-zole-6-carboxyl-ate.
| S-EPMC2984018 | biostudies-literature
Unknown 2-(4-Amino-phen-yl)-1,3-benzothia-zole.
| S-EPMC2959689 | biostudies-literature
Unknown catena-Poly[[diaqua-(1,2,3-benzothia-diazole-7-carboxyl-ato-?O)copper(II)]-?-1,2,3-benzothia-diazole-7-carboxyl-ato-?N:O].
| S-EPMC2970341 | biostudies-literature
Unknown 2-[3-(1,3-Benzothia-zol-2-yl)-2,2-di-methyl-prop-yl]-2-methyl-2,3-di-hydro-1,3-benzothia-zole.
| S-EPMC3414284 | biostudies-literature
Unknown catena-Poly[[(2,2'-dimethyl-4,4'-bi-1,3-thia-zole-?N,N')cadmium]-di-?-bromido].
| S-EPMC3152112 | biostudies-other
Unknown Bis(1,3-benzothia-zole-2-thiol-ato)[(Z)-methyl 2-(2-amino-1,3-thia-zol-4-yl)-2-(methoxy-imino)acetate]nickel(II).
| S-EPMC2979032 | biostudies-literature
Unknown 2-Amino-6-methyl-1,3-benzothia-zole-deca-nedioic acid (2/1).
| S-EPMC2970063 | biostudies-literature