Catena-Poly[[(2-amino-1,3-benzothia-zole-6-carboxyl-ato-?(2)O,O')(2,2'-bipyridyl-?(2)N,N')cadmium]-?-2-amino-1,3-benzothia-zole-6-carboxyl-ato-?(3)N(1):O,O'].
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ABSTRACT: In the title coordination polymer, [Cd(C(8)H(5)N(2)O(2)S)(2)(C(10)H(8)N(2))](n), the Cd(II) ion is coordinated by a bidentate 2,2-bipyridyl ligand, two O,O'-chelating 2-amino-1,3-benzothia-zole-6-carboxyl-ate (ABTC) ligands and one N-bonded ABTC ligand. The resulting CdN(3)O(4) coordination polyhedron approximates to a very distorted penta-gonal bipramid with one O and one N atom in axial positions. One of the ABTC ligands is bridging to an adjacent metal atom, generating an infinite chain propagating in [100]. A three-dimensional network is constructed from N-H?O and N-H?N hydrogen bonds and aromatic ?-? stacking inter-actions [centroid-centroid separations = 3.641?(2) and 3.682?(3)?Å].
SUBMITTER: Gao D
PROVIDER: S-EPMC3344366 | biostudies-literature | 2012 May
REPOSITORIES: biostudies-literature
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