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Catena-Poly[[(2-amino-pyrimidine-?N(1))(thio-cyanato-?S)mercury(II)]-?-thio-cyanato-?(2)S:N].

ABSTRACT: In the title coordination polymer, [Hg(NCS)(2)(C(4)H(5)N(3))], the Hg(II) atom is four-coordinated by one aromatic N atom from a 2-amino-pyrimidine ligand, one S atom from a terminal thio-cyanate ligand, and one S atom and one N atom from a bridging thio-cyanate ligand. The crystal structure features polymeric chains running along the b axis which are stabilized by N-H?N hydrogen bonds.

SUBMITTER: Hoseinzadeh F 

PROVIDER: S-EPMC3344369 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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catena-Poly[[(2-amino-pyrimidine-κN(1))(thio-cyanato-κS)mercury(II)]-μ-thio-cyanato-κ(2)S:N].

Hoseinzadeh Fatemeh F   Shirvan Sadif A SA   Haydari Dezfuli Sara S  

Acta crystallographica. Section E, Structure reports online 20120421 Pt 5

In the title coordination polymer, [Hg(NCS)(2)(C(4)H(5)N(3))], the Hg(II) atom is four-coordinated by one aromatic N atom from a 2-amino-pyrimidine ligand, one S atom from a terminal thio-cyanate ligand, and one S atom and one N atom from a bridging thio-cyanate ligand. The crystal structure features polymeric chains running along the b axis which are stabilized by N-H⋯N hydrogen bonds. ...[more]

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