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Aqua-trichlorido(1-cyano-methyl-4-aza-1-azoniabicyclo-[2.2.2]octane-?N(4))copper(II) monohydrate.

ABSTRACT: The asymmetric unit of the title compound, [CuCl(3)(C(8)H(14)N(3))(H(2)O)]·H(2)O, comprises a neutral complex and a mol-ecule of free water. The complex contains coordinated Cu(II) ions, with Cu-Cl distances ranging from 2.3471?(8) to 2.4011?(8)?Å, and with Cu-N and Cu-O distances of 2.0775?(19) and 2.0048?(18)?Å, respectively. The resulting coordination polyhedron is a trigonal bipyramid with the Cl atoms in the equatorial plane. In the crystal, O-H?Cl and O-H?O hydrogen bonds link the mol-ecules into a three-dimensional structure.

SUBMITTER: Zhou Q 

PROVIDER: S-EPMC3344395 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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Aqua-trichlorido(1-cyano-methyl-4-aza-1-azoniabicyclo-[2.2.2]octane-κN(4))copper(II) monohydrate.

Zhou Qinqin Q   Zhang Yi Y  

Acta crystallographica. Section E, Structure reports online 20120425 Pt 5

The asymmetric unit of the title compound, [CuCl(3)(C(8)H(14)N(3))(H(2)O)]·H(2)O, comprises a neutral complex and a mol-ecule of free water. The complex contains coordinated Cu(II) ions, with Cu-Cl distances ranging from 2.3471 (8) to 2.4011 (8) Å, and with Cu-N and Cu-O distances of 2.0775 (19) and 2.0048 (18) Å, respectively. The resulting coordination polyhedron is a trigonal bipyramid with the Cl atoms in the equatorial plane. In the crystal, O-H⋯Cl and O-H⋯O hydrogen bonds link the mol-ecul  ...[more]

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