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(Z)-2-(4-Chloro-benzyl-idene)benzo[d]thia-zolo[3,2-a]imidazol-3(2H)-one.

ABSTRACT: The mol-ecule of the title compound, C(16)H(9)ClN(2)OS, is approximately planar, the dihedral angle between the thia-zolo[3,2-a]benzimidazole ring system and the 4-chloro-phenyl ring being 2.10?(5)°. An intra-molecular C-H?S inter-action generates an S(6) ring motif. In the crystal, mol-ecules are stacked into columns along the b axis by ?-? inter-actions with centroid-centroid distances of 3.6495?(7)-3.9546?(8)?Å.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3344520 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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(Z)-2-(4-Chloro-benzyl-idene)benzo[d]thia-zolo[3,2-a]imidazol-3(2H)-one.

Fun Hoong-Kun HK Chantrapromma Suchada S Abdel-Aziz Hatem A HA

Acta crystallographica. Section E, Structure reports online 20120418 Pt 5

The mol-ecule of the title compound, C(16)H(9)ClN(2)OS, is approximately planar, the dihedral angle between the thia-zolo[3,2-a]benzimidazole ring system and the 4-chloro-phenyl ring being 2.10 (5)°. An intra-molecular C-H⋯S inter-action generates an S(6) ring motif. In the crystal, mol-ecules are stacked into columns along the b axis by π-π inter-actions with centroid-centroid distances of 3.6495 (7)-3.9546 (8) Å. ...[more]

PMID: 22590282

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