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Benzyl 3-(2-methyl-phen-yl)dithio-carbazate.

ABSTRACT: In the title compound, C(15)H(16)N(2)S(2), the central C(2)N(2)S(2) unit is essentially planar (r.m.s. deviation = 0.047?Å) and forms dihedral angles of 68.26?(4) and 65.99?(4)° with the phenyl and benzene rings, respectively, indicating a twisted mol-ecule. Supra-molecular chains with a step topology and propagating along [100] feature in the crystal packing, mediated through N-H?S hydrogen bonds. The chains are consolidated into a three-dimensional architecture by C-H?? inter-actions.

SUBMITTER: Tayamon S

PROVIDER: S-EPMC3344528 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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Benzyl 3-(2-methyl-phen-yl)dithio-carbazate.

Tayamon Shahedeh S Ravoof Thahira Begum S A TB Tahir Mohamed Ibrahim Mohamed MI Crouse Karen A KA Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20120418 Pt 5

In the title compound, C(15)H(16)N(2)S(2), the central C(2)N(2)S(2) unit is essentially planar (r.m.s. deviation = 0.047 Å) and forms dihedral angles of 68.26 (4) and 65.99 (4)° with the phenyl and benzene rings, respectively, indicating a twisted mol-ecule. Supra-molecular chains with a step topology and propagating along [100] feature in the crystal packing, mediated through N-H⋯S hydrogen bonds. The chains are consolidated into a three-dimensional architecture by C-H⋯π inter-actions. ...[more]

PMID: 22590290

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