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2,4,6,8-Tetra-kis(4-chloro-phen-yl)-3,7-diaza-bicyclo-[3.3.1]nonan-9-one O-benzyl-oxime acetone monosolvate.

ABSTRACT: In the title compound, C(38)H(31)Cl(4)N(3)O·C(3)H(6)O, the 3,7-diaza-bicycle exists in a chair-boat conformation. The 4-chloro-phenyl groups attached to the chair form are equatorially oriented at an angle of 18.15?(3)° with respect to each other, whereas the 4-chloro-phenyl groups attached to the boat form are oriented at an angle of 32.64?(3)°. In the crystal, mol-ecules are linked by N-H?? and C-H?O inter-actions.

SUBMITTER: Park DH

PROVIDER: S-EPMC3344591 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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2,4,6,8-Tetra-kis(4-chloro-phen-yl)-3,7-diaza-bicyclo-[3.3.1]nonan-9-one O-benzyl-oxime acetone monosolvate.

Park Dong Ho DH Ramkumar V V Parthiban P P

Acta crystallographica. Section E, Structure reports online 20120421 Pt 5

In the title compound, C(38)H(31)Cl(4)N(3)O·C(3)H(6)O, the 3,7-diaza-bicycle exists in a chair-boat conformation. The 4-chloro-phenyl groups attached to the chair form are equatorially oriented at an angle of 18.15 (3)° with respect to each other, whereas the 4-chloro-phenyl groups attached to the boat form are oriented at an angle of 32.64 (3)°. In the crystal, mol-ecules are linked by N-H⋯π and C-H⋯O inter-actions. ...[more]

PMID: 22590353

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