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N-(2,6-Diisopropyl-phen-yl)formamide toluene 0.33-solvate.

ABSTRACT: The crystal packing of the title compound, C(13)H(19)NO·0.33C(7)H(8), shows a channel at [001], which contains grossly disordered toluene solvent mol-ecules. The angle between the benzene ring and the mean plane of the formamide group is 71.1?(1)°. The amide groups of neighbouring mol-ecules are connected by N-H?O hydrogen bonds, forming 2(1) helical chains propagating along [001]. Mol-ecules are also connected by weak inter-molecular C-H?O hydrogen bonds, forming 6(1) helices.

SUBMITTER: Berger M

PROVIDER: S-EPMC3344661 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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N-(2,6-Diisopropyl-phen-yl)formamide toluene 0.33-solvate.

Berger Matthias M Bats Jan W JW Auner Norbert N

Acta crystallographica. Section E, Structure reports online 20120428 Pt 5

The crystal packing of the title compound, C(13)H(19)NO·0.33C(7)H(8), shows a channel at [001], which contains grossly disordered toluene solvent mol-ecules. The angle between the benzene ring and the mean plane of the formamide group is 71.1 (1)°. The amide groups of neighbouring mol-ecules are connected by N-H⋯O hydrogen bonds, forming 2(1) helical chains propagating along [001]. Mol-ecules are also connected by weak inter-molecular C-H⋯O hydrogen bonds, forming 6(1) helices. ...[more]

PMID: 22590423

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