Dataset Information

Traversing Material Scales: Macroscale LBL-Assembled Nanocomposites with Microscale Inverted Colloidal Crystal Architecture.

ABSTRACT: The introduction of three-dimensional (3D) architecture to functional materials allows for the addition of unique characteristics such as special deformation patterns, negative Poison's ratio, negative thermal expansion, controlled biological interactions, and mass transport properties. It also aids in bridging the dimensional gap between layer-by-layer (LBL) assembled nanocomposites and macroscale applications while retaining the advantages of their nanoscale organization. Fabrication of 3D microscale features by traditional techniques are often restricted to a limited variety of materials and do not include hybrid organic-inorganic nanocomposites. This work describes a new method to synthesize macroscale materials with hierarchically controlled architecture by using LBL deposition in the voids of hexagonally packed arrays of uniform microspheres and can be potentially extended to a large variety of materials. Establishing systematic techniques to produce materials with hierarchical architecture involving nano-, micro-, and potentially millimeter scale features with fairly independent control at all levels, allows for the investigation of structural influences on material properties and for the development of new practical applications due to the unusual combinations of properties that can be achieved.

SUBMITTER: Andres CM

PROVIDER: S-EPMC3359643 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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Publications

Traversing Material Scales: Macroscale LBL-Assembled Nanocomposites with Microscale Inverted Colloidal Crystal Architecture.

Andres Christine M CM Fox Mary L ML Kotov Nicholas A NA

Chemistry of materials : a publication of the American Chemical Society 20111206 1

The introduction of three-dimensional (3D) architecture to functional materials allows for the addition of unique characteristics such as special deformation patterns, negative Poison's ratio, negative thermal expansion, controlled biological interactions, and mass transport properties. It also aids in bridging the dimensional gap between layer-by-layer (LBL) assembled nanocomposites and macroscale applications while retaining the advantages of their nanoscale organization. Fabrication of 3D mic ...[more]

PMID: 22639491

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Project description:Green infrastructure (GI) in urban areas may be adopted as a passive control system to reduce air pollutant concentrations. However, current dispersion models offer limited modelling options to evaluate its impact on ambient pollutant concentrations. The scope of this review revolves around the following question: how can GI be considered in readily available dispersion models to allow evaluation of its impacts on pollutant concentrations and health risk assessment? We examined the published literature on the parameterisation of deposition velocities and datasets for both particulate matter and gaseous pollutants that are required for deposition schemes. We evaluated the limitations of different air pollution dispersion models at two spatial scales - microscale (i.e. 10-500?m) and macroscale (i.e. 5-100?km) - in considering the effects of GI on air pollutant concentrations and exposure alteration. We conclude that the deposition schemes that represent GI impacts in detail are complex, resource-intensive, and involve an abundant volume of input data. An appropriate handling of GI characteristics (such as aerodynamic effect, deposition of air pollutants and surface roughness) in dispersion models is necessary for understanding the mechanism of air pollutant concentrations simulation in presence of GI at different spatial scales. The impacts of GI on air pollutant concentrations and health risk assessment (e.g., mortality, morbidity) are partly explored. The i-Tree tool with the BenMap model has been used to estimate the health outcomes of annually-averaged air pollutant removed by deposition over GI canopies at the macroscale. However, studies relating air pollution health risk assessments due to GI-related changes in short-term exposure, via pollutant concentrations redistribution at the microscale and enhanced atmospheric pollutant dilution by increased surface roughness at the macroscale, along with deposition, are rare. Suitable treatments of all physical and chemical processes in coupled dispersion-deposition models and assessments against real-world scenarios are vital for health risk assessments.

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Dataset Information

Traversing Material Scales: Macroscale LBL-Assembled Nanocomposites with Microscale Inverted Colloidal Crystal Architecture.

Publications

Traversing Material Scales: Macroscale LBL-Assembled Nanocomposites with Microscale Inverted Colloidal Crystal Architecture.

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