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Construction of 1,5-enynes by stereospecific Pd-catalyzed allyl-propargyl cross-couplings.

ABSTRACT: The palladium-catalyzed cross-coupling of chiral propargyl acetates and allyl boronates delivers chiral 1,5-enynes with excellent levels of chirality transfer and can be applied across a broad range of substrates.

SUBMITTER: Ardolino MJ 

PROVIDER: S-EPMC3374959 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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Construction of 1,5-enynes by stereospecific Pd-catalyzed allyl-propargyl cross-couplings.

Ardolino Michael J MJ   Morken James P JP  

Journal of the American Chemical Society 20120517 21

The palladium-catalyzed cross-coupling of chiral propargyl acetates and allyl boronates delivers chiral 1,5-enynes with excellent levels of chirality transfer and can be applied across a broad range of substrates. ...[more]

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