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Bis(?-diisopropyl-phosphanido-?(2)P:P)bis-[hydrido(triisopropyl-phosphane-?P)platinum(II)].

ABSTRACT: In the centrosymmetric mol-ecular structure of the title compound [Pt(2)(C(6)H(14)P)(2)H(2)(C(9)H(21)P)(2)], each Pt(II) atom is bound on one side to a phosphane ligand (PiPr(3)) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands (?-PiPr(2)), which engage a bridging position between the two Pt(II) atoms, forming a distorted square-planar structure motif. The Pt?Pt distance is 3.6755?(2)?Å. A comparable mol-ecular structure was observed for bis-(?-di-tert-butyl-phosphanido)bis-[hydrido(triethyl-phosphane)platinum(II)] [Itazaki et al. (2004 ?). Organometallics, 23, 1610-1621].

SUBMITTER: Arnold N 

PROVIDER: S-EPMC3379133 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Bis(μ-diisopropyl-phosphanido-κ(2)P:P)bis-[hydrido(triisopropyl-phosphane-κP)platinum(II)].

Arnold Nicole N   Braunschweig Holger H   Damme Alexander A  

Acta crystallographica. Section E, Structure reports online 20120526 Pt 6

In the centrosymmetric mol-ecular structure of the title compound [Pt(2)(C(6)H(14)P)(2)H(2)(C(9)H(21)P)(2)], each Pt(II) atom is bound on one side to a phosphane ligand (PiPr(3)) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands (μ-PiPr(2)), which engage a bridging position between the two Pt(II) atoms, forming a distorted square-planar structure motif. The Pt⋯Pt distance is 3.6755 (2) Å. A comparable mol-ecular structure was observed for bis-(μ-di-tert-butyl-phosph  ...[more]

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