Ontology highlight
ABSTRACT:
SUBMITTER: Zhang J
PROVIDER: S-EPMC3379183 | biostudies-literature | 2012 Jun
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20120531 Pt 6
In the title compound, {[Tb(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), the polymeric anionic chain {[AgWS(4)](-)}(n) extends along [001]. The Tb(III) atom in the cation is coordinated by eight O atoms from two nitrate and four hexamethylphosphate ligands in a distorted square-anti-prismatic geometry. Together with the two nitrate ligands, the cation is univalent, which leads to the anionic chain having a [WS(4)Ag] repeat unit. The polymeric anionic chain has a distorted linear configuration wi ...[more]