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Di-?-aqua-bis-{diaqua-[?-4-({4-[bis-(2-hy-droxy-eth-yl)amino]-6-chloro-1,3,5-triazin-2-yl}amino)-benzene-sulfonato]-sodium(I)}.


ABSTRACT: In the dinuclear title compound, [Na(2)(C(13)H(15)ClN(5)O(5)S)(2)(H(2)O)(6)](n), two Na(+) cations, disposed about a centre of inversion, are linked by two bridging water mol-ecules. The coordination geometry is based on an O(5) donor set defined by four water mol-ecules and a 4-amino-benzene-sulfonate O atom in a distorted trigonal-bipyramidal geometry. In the crystal, significant O-H?O, O-H?N and N-H?O hydrogen bonds lead to the formation of a three-dimensional architecture.

SUBMITTER: Zhang M 

PROVIDER: S-EPMC3379186 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Di-μ-aqua-bis-{diaqua-[μ-4-({4-[bis-(2-hy-droxy-eth-yl)amino]-6-chloro-1,3,5-triazin-2-yl}amino)-benzene-sulfonato]-sodium(I)}.

Zhang Mei M   Sun Fu-Yu FY   Zhao Gui-Zhe GZ   Liu Ya-Qing YQ  

Acta crystallographica. Section E, Structure reports online 20120531 Pt 6


In the dinuclear title compound, [Na(2)(C(13)H(15)ClN(5)O(5)S)(2)(H(2)O)(6)](n), two Na(+) cations, disposed about a centre of inversion, are linked by two bridging water mol-ecules. The coordination geometry is based on an O(5) donor set defined by four water mol-ecules and a 4-amino-benzene-sulfonate O atom in a distorted trigonal-bipyramidal geometry. In the crystal, significant O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonds lead to the formation of a three-dimensional architecture. ...[more]

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