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N-[2-(2-Hy-droxy-eth-oxy)pheneth-yl]phthalimide.

ABSTRACT: The title compound, C(18)H(17)NO(4), was obtained accidentally through acid-catalysed aromatization of a phthalimide-substituted 2-(1-hy-droxy-eth-yl)cyclo-hex-2-enone. It exhibits an intra-molecular O-H?O(c) (c = carbonyl) hydrogen bond and forms a three-dimensional network structure via ?-? stacking inter-actions between adjacent benzene rings (phthalimide-to-phenyl-ene and phthalimide-to-phthalimide), with centroid-centroid distances of 3.8262?(6) and 3.6245?(5)?Å.

SUBMITTER: Yang EQ

PROVIDER: S-EPMC3379239 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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N-[2-(2-Hy-droxy-eth-oxy)pheneth-yl]phthalimide.

Yang Er-Qun EQ Zhang Jun-Tao JT Cao Xiao-Ping XP Gu Jin-Zhong JZ

Acta crystallographica. Section E, Structure reports online 20120505 Pt 6

The title compound, C(18)H(17)NO(4), was obtained accidentally through acid-catalysed aromatization of a phthalimide-substituted 2-(1-hy-droxy-eth-yl)cyclo-hex-2-enone. It exhibits an intra-molecular O-H⋯O(c) (c = carbonyl) hydrogen bond and forms a three-dimensional network structure via π-π stacking inter-actions between adjacent benzene rings (phthalimide-to-phenyl-ene and phthalimide-to-phthalimide), with centroid-centroid distances of 3.8262 (6) and 3.6245 (5) Å. ...[more]

PMID: 22719437

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