Unknown

Dataset Information

0

(E)-3-Dimethyl-amino-1-(2,5-dimethyl-thio-phen-3-yl)prop-2-en-1-one.

ABSTRACT: In the title compound, C(11)H(15)NOS, the 3-(dimethyl-amino)-prop-2-en-1-one unit is approximately planar [maximum deviation = 0.0975?(14)?Å] and its mean plane of seven non-H atoms makes a dihedral angle of 6.96?(10)° with the thio-phene ring. In the crystal, mol-ecules are linked by pairs of C-H?O hydrogen bonds into inversion dimers with R(2) (2)(14) ring motifs. The dimers are stacked along the c axis through C-H?? inter-actions. The two methyl groups, attached to the thio-phene ring and the amino N atom, are each disordered over two orientations, with site-occupancy ratios of 0.59?(4):0.41?(4) and 0.74?(4):0.26?(4), respectively.

SUBMITTER: Ghorab MM 

PROVIDER: S-EPMC3379305 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

(E)-3-Dimethyl-amino-1-(2,5-dimethyl-thio-phen-3-yl)prop-2-en-1-one.

Ghorab Mostafa M MM   Al-Said Mansour S MS   Ghabbour Hazem A HA   Chia Tze Shyang TS   Fun Hoong-Kun HK  

Acta crystallographica. Section E, Structure reports online 20120512 Pt 6

In the title compound, C(11)H(15)NOS, the 3-(dimethyl-amino)-prop-2-en-1-one unit is approximately planar [maximum deviation = 0.0975 (14) Å] and its mean plane of seven non-H atoms makes a dihedral angle of 6.96 (10)° with the thio-phene ring. In the crystal, mol-ecules are linked by pairs of C-H⋯O hydrogen bonds into inversion dimers with R(2) (2)(14) ring motifs. The dimers are stacked along the c axis through C-H⋯π inter-actions. The two methyl groups, attached to the thio-phene ring and the  ...[more]

Similar Datasets

Unknown (2E)-1-(2,5-Dimethyl-thio-phen-3-yl)-3-(3-nitro-phen-yl)prop-2-en-1-one.
| S-EPMC3238980 | biostudies-literature
Unknown (2E)-3-(3,4-Dimeth-oxy-phen-yl)-1-(2,5-dimethyl-thio-phen-3-yl)prop-2-en-1-one.
| S-EPMC3007254 | biostudies-literature
Unknown (2E)-3-[4-(Dimethyl-amino)-phen-yl]-1-(2,5-dimethyl-3-thien-yl)prop-2-en-1-one.
| S-EPMC3008074 | biostudies-literature
Unknown (E)-1-(2,5-Dichloro-3-thien-yl)-3-[4-(dimethyl-amino)phen-yl]prop-2-en-1-one.
| S-EPMC2979294 | biostudies-literature
Unknown (E)-1-(2-Amino-phen-yl)-3-(thio-phen-2-yl)prop-2-en-1-one.
| S-EPMC3772449 | biostudies-literature
Unknown 3-Dimethyl-amino-1-(4-methyl-phen-yl)prop-2-en-1-one.
| S-EPMC2980110 | biostudies-literature
Unknown (E)-3-[4-(Dimethyl-amino)phen-yl]-1-(4-methyl-phen-yl)prop-2-en-1-one.
| S-EPMC2980133 | biostudies-literature
Unknown (E)-1-(4-Chloro-phen-yl)-3-[4-(dimethyl-amino)phen-yl]prop-2-en-1-one.
| S-EPMC2968919 | biostudies-literature
Unknown (2E)-3-[4-(Dimethyl-amino)-phen-yl]-1-(4-fluoro-phen-yl)prop-2-en-1-one.
| S-EPMC3051752 | biostudies-literature
Unknown 3-[4-(Dimethyl-amino)phen-yl]-1-(2-pyrrol-yl)prop-2-en-1-one.
| S-EPMC2961564 | biostudies-literature