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2-[(2,6-Diisopropyl-phen-yl)imino-meth-yl]-4-iodo-phenol.

ABSTRACT: The asymmetric unit of title compound, C(19)H(22)INO, contains two independent mol-ecules. Classical intra-molecular O-H?N hydrogen bonds stabilize the mol-ecular structures. The crystal structure is stabilized by weak inter-molecular C-H?? and ?-? [centroid-centroid = 3.8622?(18)?Å] inter-actions. In both mol-ecules, the aromatic rings are nearly perpendicular to each other [dihedral angles = 84.26?(17) and 86.69?(15)°].

SUBMITTER: Balamurugan P

PROVIDER: S-EPMC3379471 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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2-[(2,6-Diisopropyl-phen-yl)imino-meth-yl]-4-iodo-phenol.

Balamurugan P P Raja K Kanmani KK Bilal I Mohammed IM Chakkaravarthi G G Rajagopal G G

Acta crystallographica. Section E, Structure reports online 20120531 Pt 6

The asymmetric unit of title compound, C(19)H(22)INO, contains two independent mol-ecules. Classical intra-molecular O-H⋯N hydrogen bonds stabilize the mol-ecular structures. The crystal structure is stabilized by weak inter-molecular C-H⋯π and π-π [centroid-centroid = 3.8622 (18) Å] inter-actions. In both mol-ecules, the aromatic rings are nearly perpendicular to each other [dihedral angles = 84.26 (17) and 86.69 (15)°]. ...[more]

PMID: 22719669

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4-Chloro-2-[(2,6-diisopropyl-phen-yl)imino-meth-yl]phenol.

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