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Cis-Diamminedichloridoplatinum(II) N,N-dimethyl-formamide monosolvate.

ABSTRACT: In the title compound, cis-[PtCl?(NH?)?]·C?H?NO, the metal complex mol-ecules are stacked parallel to the b axis, forming close Pt?Pt inter-actions of 3.4071?(7) and 3.5534?(8)?Å and weak N-H?Cl hydrogen bonds between the ammine ligand and the Cl atoms of the neighboring complex. Conventional N-H?O hydrogen bonds are formed between ammine ligands and the O atom of adjacent N,N-dimethyl-formamide mol-ecules. The crystal was found to be a split crystal and was analyzed using two domains related by a rotation of ca 4.4° about the reciprocal axis (-0.351 1.000 0.742) and refined to give a minor component fraction of 0.084?(6).

SUBMITTER: Johnston DH

PROVIDER: S-EPMC3393146 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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cis-Diamminedichloridoplatinum(II) N,N-dimethyl-formamide monosolvate.

Johnston Dean H DH Miller Nathanael A NA Tackett Cory B CB

Acta crystallographica. Section E, Structure reports online 20120602 Pt 7

In the title compound, cis-[PtCl₂(NH₃)₂]·C₃H₇NO, the metal complex mol-ecules are stacked parallel to the b axis, forming close Pt⋯Pt inter-actions of 3.4071 (7) and 3.5534 (8) Å and weak N-H⋯Cl hydrogen bonds between the ammine ligand and the Cl atoms of the neighboring complex. Conventional N-H⋯O hydrogen bonds are formed between ammine ligands and the O atom of adjacent N,N-dimethyl-formamide mol-ecules. The crystal was found to be a split crystal and was analyzed using two domains related by ...[more]

PMID: 22807714

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