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Poly[??-aqua-??-(2-{3-[(6-chloro-pyridin-3-yl)meth-yl]-2-oxoimidazolidin-1-yl}acetato)-sodium].

ABSTRACT: In the title compound, [Na(C??H??ClN?O?)(H?O)](n), there are two independent Na(I) ions, one of which lies on an inversion center and is coordinated in a slightly distorted octa-hedral environment. The other Na(I) ion lies on a twofold rotation axis and is cooordinated in a slightly distorted trigonal-bipyramidal coordination environment. In the organic ligand, the imidazolidine ring adopts a half-chair conformation. The Na(I) ions bridge organic ligands and water mol-ecules, forming a two-dimensional structure parallel to (100). There are inter-molecular O-H?O and weak C-H?O hydrogen bonds within the two-dimensional structure.

SUBMITTER: Kant R

PROVIDER: S-EPMC3393166 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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Poly[μ₂-aqua-μ₄-(2-{3-[(6-chloro-pyridin-3-yl)meth-yl]-2-oxoimidazolidin-1-yl}acetato)-sodium].

Kant Rajni R Gupta Vivek K VK Kapoor Kamini K Shripanavar Chetan S CS Banerjee Kaushik K Deshmukh Madhukar B MB

Acta crystallographica. Section E, Structure reports online 20120613 Pt 7

In the title compound, [Na(C₁₁H₁₁ClN₃O₃)(H₂O)](n), there are two independent Na(I) ions, one of which lies on an inversion center and is coordinated in a slightly distorted octa-hedral environment. The other Na(I) ion lies on a twofold rotation axis and is cooordinated in a slightly distorted trigonal-bipyramidal coordination environment. In the organic ligand, the imidazolidine ring adopts a half-chair conformation. The Na(I) ions bridge organic ligands and water mol-ecules, forming a two-dimen ...[more]

PMID: 22807734

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