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(Bipyridine-?(2)N,N')chlorido[N-(2-hydroxy-ethyl)-N-isopropyl-dithio-carbamato-?(2)S,S']zinc(II).

ABSTRACT: The Zn(II) atom in the title compound, [Zn(C(6)H(12)NOS(2))Cl(C(10)H(8)N(2))], is coordinated by a chelating N-2-hy-droxy-ethyl-N-isopropyl-dithio-carbamate ligand, a 2,2'-bipyridine ligand and a Cl atom. The resulting ClN(2)S(2) donor set defines a distorted square-pyramidal coordination geometry. Helical supra-molecular chains sustained by O-H?S hydrogen bonds and propagating along the b axis feature in the crystal packing. A three-dimensional architecture is stabilized by C-H?O, C-H?S and C-H?Cl inter-actions.

SUBMITTER: Mohamad FA

PROVIDER: S-EPMC3393212 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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(Bipyridine-κ(2)N,N')chlorido[N-(2-hydroxy-ethyl)-N-isopropyl-dithio-carbamato-κ(2)S,S']zinc(II).

Mohamad Fatin Allia FA Baba Ibrahim I Mohamed Tahir Mohamed Ibrahim MI Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20120623 Pt 7

The Zn(II) atom in the title compound, [Zn(C(6)H(12)NOS(2))Cl(C(10)H(8)N(2))], is coordinated by a chelating N-2-hy-droxy-ethyl-N-isopropyl-dithio-carbamate ligand, a 2,2'-bipyridine ligand and a Cl atom. The resulting ClN(2)S(2) donor set defines a distorted square-pyramidal coordination geometry. Helical supra-molecular chains sustained by O-H⋯S hydrogen bonds and propagating along the b axis feature in the crystal packing. A three-dimensional architecture is stabilized by C-H⋯O, C-H⋯S and C-H ...[more]

PMID: 22807780

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