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Dibromido[methyl 2-(quinolin-8-yl-oxy-?(2)N,O)acetic acid-?O]mercury(II).

ABSTRACT: In the title complex, [HgBr(2)(C(12)H(11)NO(3))], the Hg(II) ion has a distorted core trigonal-planar geometry comprising two Br atoms and one quinoline N atom of the methyl 2-(quinolin-8-yl-oxy)acetic acid ligand. The angles around the Hg atom vary from 100.31?(15) to 152.65?(4)°. Two additional Hg?O inter-actions [2.739?(1) and 2.905?(1)?Å] complete the coordination sphere about the Hg(II) atom.

SUBMITTER: Song RF

PROVIDER: S-EPMC3393219 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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Dibromido[methyl 2-(quinolin-8-yl-oxy-κ(2)N,O)acetic acid-κO]mercury(II).

Song Rui-Feng RF Zhu Xue-Hua XH Wang Yu-Hong YH

Acta crystallographica. Section E, Structure reports online 20120623 Pt 7

In the title complex, [HgBr(2)(C(12)H(11)NO(3))], the Hg(II) ion has a distorted core trigonal-planar geometry comprising two Br atoms and one quinoline N atom of the methyl 2-(quinolin-8-yl-oxy)acetic acid ligand. The angles around the Hg atom vary from 100.31 (15) to 152.65 (4)°. Two additional Hg⋯O inter-actions [2.739 (1) and 2.905 (1) Å] complete the coordination sphere about the Hg(II) atom. ...[more]

PMID: 22807787

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