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4-Methyl-anilinium 2-carb-oxy-acetate.

ABSTRACT: During the formation of the title salt, C(7)H(10)N(+)·C(3)H(3)O(4) (-), an H atom of a carboxyl group was transferred to the amino group. All non-H atoms of the cation are essentially coplanar [r.m.s. deviation = 0.007?(4)?Å]. The mean planes of the carboxyl-ate and carboxyl groups of the anion form a dihedral of 69.67?(1)°. In the crystal, N-H?O and O-H?O hydrogen bonds connect the anions and cations, forming a two-dimensional network parallel to the bc plane.

SUBMITTER: Wang YC

PROVIDER: S-EPMC3393260 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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4-Methyl-anilinium 2-carb-oxy-acetate.

Wang Ying-Chun YC

Acta crystallographica. Section E, Structure reports online 20120602 Pt 7

During the formation of the title salt, C(7)H(10)N(+)·C(3)H(3)O(4) (-), an H atom of a carboxyl group was transferred to the amino group. All non-H atoms of the cation are essentially coplanar [r.m.s. deviation = 0.007 (4) Å]. The mean planes of the carboxyl-ate and carboxyl groups of the anion form a dihedral of 69.67 (1)°. In the crystal, N-H⋯O and O-H⋯O hydrogen bonds connect the anions and cations, forming a two-dimensional network parallel to the bc plane. ...[more]

PMID: 22807817

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