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2-Cyano-N'-[(E)-1-(2-oxo-2H-chromen-3-yl)ethyl-idene]acetohydrazide.

ABSTRACT: In the title compound, C(14)H(11)N(3)O(3), the chromene ring is almost planar, with a maximum deviation of 0.065?(2)?Å from the mean plane for one of the C atoms. In the crystal, inversion dimers linked by pairs of N-H?O hydrogen bonds generate R(2) (2)(8) loops. The dimers are linked by C-H?N and C-H?O inter-actions into a three-dimensional network. An aromatic ?-? stacking inter-action, with a centroid-centroid distance of 3.562?(10)?Å, is also observed.

SUBMITTER: Yusufzai SK

PROVIDER: S-EPMC3393277 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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2-Cyano-N'-[(E)-1-(2-oxo-2H-chromen-3-yl)ethyl-idene]acetohydrazide.

Yusufzai Samina Khan SK Osman Hasnah H Wahab Habibah A HA Rosli Mohd Mustaqim MM Razak Ibrahim Abdul IA

Acta crystallographica. Section E, Structure reports online 20120613 Pt 7

In the title compound, C(14)H(11)N(3)O(3), the chromene ring is almost planar, with a maximum deviation of 0.065 (2) Å from the mean plane for one of the C atoms. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R(2) (2)(8) loops. The dimers are linked by C-H⋯N and C-H⋯O inter-actions into a three-dimensional network. An aromatic π-π stacking inter-action, with a centroid-centroid distance of 3.562 (10) Å, is also observed. ...[more]

PMID: 22807834

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