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2-(3-Meth-oxy-phen-yl)-1,3-dihydro-1,3,2-benzodiaza-borole.

ABSTRACT: The title compound, C(13)H(13)BN(2)O, is one in a series of 1,3,2-benzodiaza-boroles featuring a 2-meth-oxy-phenyl substitution at the 2-position in the nitro-gen-boron heterocyle. The dihedral angle between the mean planes of the benzodiaza-borole and 2-meth-oxy-phenyl ring systems is 21.5?(1)°. There is an inter-molecular hydrogen bond between one of the NH groups and the meth-oxy O atom. This hydrogen bond leads to an infinite hydrogen-bonded chain colinear with the a axis.

SUBMITTER: Robinson RS

PROVIDER: S-EPMC3394032 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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2-(3-Meth-oxy-phen-yl)-1,3-dihydro-1,3,2-benzodiaza-borole.

Robinson Ross S RS Sithebe Siphamandla S Akerman Matthew P MP

Acta crystallographica. Section E, Structure reports online 20120630 Pt 7

The title compound, C(13)H(13)BN(2)O, is one in a series of 1,3,2-benzodiaza-boroles featuring a 2-meth-oxy-phenyl substitution at the 2-position in the nitro-gen-boron heterocyle. The dihedral angle between the mean planes of the benzodiaza-borole and 2-meth-oxy-phenyl ring systems is 21.5 (1)°. There is an inter-molecular hydrogen bond between one of the NH groups and the meth-oxy O atom. This hydrogen bond leads to an infinite hydrogen-bonded chain colinear with the a axis. ...[more]

PMID: 22798897

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