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2-[(1H-Benzimidazol-2-yl)sulfan-yl]-1-phenyl-ethanone.

ABSTRACT: The title compound, C(15)H(12)N(2)OS, adopts a twisted V-shape, with the S atom as the pivot. The benzimidazole ring system [maximum deviation = 0.015?(1)?Å] makes a dihedral angle of 78.56?(7)° with the phenyl ring. The O atom of the ketone group is close to coplanar with its adjacent ring [O-C-C-C torsion angle = 11.0?(2)°]. In the crystal, mol-ecules are linked by N-H?N hydrogen bonds into an infinite chain along [001]. The crystal packing also features a C-H?? inter-action.

SUBMITTER: Abdel-Aziz HA

PROVIDER: S-EPMC3394045 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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2-[(1H-Benzimidazol-2-yl)sulfan-yl]-1-phenyl-ethanone.

Abdel-Aziz Hatem A HA Chia Tze Shyang TS Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20120630 Pt 7

The title compound, C(15)H(12)N(2)OS, adopts a twisted V-shape, with the S atom as the pivot. The benzimidazole ring system [maximum deviation = 0.015 (1) Å] makes a dihedral angle of 78.56 (7)° with the phenyl ring. The O atom of the ketone group is close to coplanar with its adjacent ring [O-C-C-C torsion angle = 11.0 (2)°]. In the crystal, mol-ecules are linked by N-H⋯N hydrogen bonds into an infinite chain along [001]. The crystal packing also features a C-H⋯π inter-action. ...[more]

PMID: 22798910

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