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1-Chloro-1-[(Z)-2-phenyl-hydrazin-1-yl-idene]propan-2-one.

ABSTRACT: The title compound, C(9)H(9)ClN(2)O, is close to planar (r.m.s. deviation for the non-H atoms = 0.0446 Å); it exists in a cis conformation with respect to the C=N double bond. In the crystal, the ketone O atom accepts both N-H⋯O and C-H⋯O hydrogen bonds, which leads to [010] infinite chains incorporating R(2) (1)(6) loops. The crystal structure also features a C-H⋯π inter-action.

SUBMITTER: Abdel-Aziz HA 

PROVIDER: S-EPMC3394046 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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1-Chloro-1-[(Z)-2-phenyl-hydrazin-1-yl-idene]propan-2-one.

Abdel-Aziz Hatem A HA   Chia Tze Shyang TS   Fun Hoong-Kun HK  

Acta crystallographica. Section E, Structure reports online 20120630 Pt 7

The title compound, C(9)H(9)ClN(2)O, is close to planar (r.m.s. deviation for the non-H atoms = 0.0446 Å); it exists in a cis conformation with respect to the C=N double bond. In the crystal, the ketone O atom accepts both N-H⋯O and C-H⋯O hydrogen bonds, which leads to [010] infinite chains incorporating R(2) (1)(6) loops. The crystal structure also features a C-H⋯π inter-action. ...[more]

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