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1-(2-Chloro-benz-yl)-3-methyl-2,6-diphenyl-piperidine.

ABSTRACT: In the title compound, C(25)H(26)ClN, the piperidine ring has a chair conformation with all ring substituents in equatorial positions. The dihedral angle formed between the chloro-benzene ring and the flanking phenyl rings are 74.91?(18) and 47.86?(17)°. The chloro substituent is anti to the piperidine N atom. In the crystal, centrosymmetrically related mol-ecules aggregate via ?-? inter-actions occurring between chloro-benzene rings [centroid-centroid distance = 3.778?(2)?Å] and these are linked into linear supra-molecular chains along the a axis by C-H?? inter-actions occurring between the phenyl rings.

SUBMITTER: Ramalingan C 

PROVIDER: S-EPMC3394076 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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1-(2-Chloro-benz-yl)-3-methyl-2,6-diphenyl-piperidine.

Ramalingan Chennan C   Ng Seik Weng SW   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20120630 Pt 7

In the title compound, C(25)H(26)ClN, the piperidine ring has a chair conformation with all ring substituents in equatorial positions. The dihedral angle formed between the chloro-benzene ring and the flanking phenyl rings are 74.91 (18) and 47.86 (17)°. The chloro substituent is anti to the piperidine N atom. In the crystal, centrosymmetrically related mol-ecules aggregate via π-π inter-actions occurring between chloro-benzene rings [centroid-centroid distance = 3.778 (2) Å] and these are linke  ...[more]

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