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(Acetyl-acetonato-?(2)O,O')bis-{5-fluoro-2-[3-(4-fluoro-phen-yl)pyrazin-2-yl]phenyl-?(2)N(1),C(1)}iridium(III).


ABSTRACT: In the title complex, [Ir(C(16)H(9)F(2)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom, lying on a twofold rotation axis, is hexa-coordinated in a distorted octa-hedral geometry by two C,N-bidentate 5-fluoro-2-[3-(4-fluoro-phen-yl)pyrazin-2-yl]phenyl ligands and one O,O'-bidentate acetyl-acetonate ligand. The dihedral angles between the benzene rings and the pyrazine ring are 14.66?(8) and 49.76?(12)°.

SUBMITTER: Ge GP 

PROVIDER: S-EPMC3414137 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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(Acetyl-acetonato-κ(2)O,O')bis-{5-fluoro-2-[3-(4-fluoro-phen-yl)pyrazin-2-yl]phenyl-κ(2)N(1),C(1)}iridium(III).

Ge Guo-Ping GP   Li Chun-Yan CY  

Acta crystallographica. Section E, Structure reports online 20120718 Pt 8


In the title complex, [Ir(C(16)H(9)F(2)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom, lying on a twofold rotation axis, is hexa-coordinated in a distorted octa-hedral geometry by two C,N-bidentate 5-fluoro-2-[3-(4-fluoro-phen-yl)pyrazin-2-yl]phenyl ligands and one O,O'-bidentate acetyl-acetonate ligand. The dihedral angles between the benzene rings and the pyrazine ring are 14.66 (8) and 49.76 (12)°. ...[more]

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