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{4,4',6,6'-Tetra-iodo-2,2'-[propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato-?(4)O,N,N',O'}nickel(II).

ABSTRACT: The asymmetric unit of the title compound, [Ni(C(17)H(12)I(4)N(2)O(2))], comprises half of a Schiff base complex. The Ni(II) and central C atom of the propyl chain are located on a twofold rotation axis. The geometry around the Ni(II) atom is square planar, supported by the N(2)O(2) donor atoms of the coordinated ligand. In the crystal, there are no significant inter-molecular inter-actions present. The crystal studied was a non-merohedral twin with a refined twin component ratio of 0.944?(1):0.056?(1).

SUBMITTER: Kargar H

PROVIDER: S-EPMC3414144 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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{4,4',6,6'-Tetra-iodo-2,2'-[propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato-κ(4)O,N,N',O'}nickel(II).

Kargar Hadi H Kia Reza R Adabi Ardakani Amir A Tahir Muhammad Nawaz MN

Acta crystallographica. Section E, Structure reports online 20120718 Pt 8

The asymmetric unit of the title compound, [Ni(C(17)H(12)I(4)N(2)O(2))], comprises half of a Schiff base complex. The Ni(II) and central C atom of the propyl chain are located on a twofold rotation axis. The geometry around the Ni(II) atom is square planar, supported by the N(2)O(2) donor atoms of the coordinated ligand. In the crystal, there are no significant inter-molecular inter-actions present. The crystal studied was a non-merohedral twin with a refined twin component ratio of 0.944 (1):0. ...[more]

PMID: 22904751

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