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(Ethano-lato-?O)[N'-(3-meth-oxy-2-oxidobenzyl-idene-?O(2))benzo-hydrazidato-?(2)N',O]oxidovanadium(V).

ABSTRACT: In the title complex, [V(C(15)H(12)N(2)O(4))(C(2)H(5)O)O], the V(V) ion is coordinated by an oxide O atom, an ethano-late anion and two O atoms and one N atom from the tridentate benzo-hydrazidate dianion in a distorted square-pyramidal geometry; the V atom is displaced by 0.4748?(8)?Å from the basal plane towards the axial oxide O atom. An intra-molecular O-H?N hydrogen bond occurs in the benzohydrazidate ligand. Weak inter-molecular C-H?O hydrogen bonding is present in the crystal.

SUBMITTER: Chen XH

PROVIDER: S-EPMC3414151 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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(Ethano-lato-κO)[N'-(3-meth-oxy-2-oxidobenzyl-idene-κO(2))benzo-hydrazidato-κ(2)N',O]oxidovanadium(V).

Chen Xiao-Hua XH Wu Qiong-Jie QJ Chen Li-Juan LJ Yang Ming-Xing MX

Acta crystallographica. Section E, Structure reports online 20120721 Pt 8

In the title complex, [V(C(15)H(12)N(2)O(4))(C(2)H(5)O)O], the V(V) ion is coordinated by an oxide O atom, an ethano-late anion and two O atoms and one N atom from the tridentate benzo-hydrazidate dianion in a distorted square-pyramidal geometry; the V atom is displaced by 0.4748 (8) Å from the basal plane towards the axial oxide O atom. An intra-molecular O-H⋯N hydrogen bond occurs in the benzohydrazidate ligand. Weak inter-molecular C-H⋯O hydrogen bonding is present in the crystal. ...[more]

PMID: 22904758

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