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Catena-Poly[[(2-{[2-(dimethyl-ammonio)-eth-yl]imino-meth-yl}pyridine-?(2)N,N')bis-(thio-cyanato-?N)manganese(II)]-?-thio-cyanato-?(2)N:S].

ABSTRACT: In the title one-dimensional coordination polymer, [Mn(NCS)(3)(C(10)H(16)N(3))](n), the Mn(II) atom is coordinated by an N,N'-bidentate Schiff base and four thio-cyanate ligands in a distorted octa-hedral N(5)S geometry. Bridging thio-cyanate ligands inter-connect adjacent [Mn(NCS)(2)(C(10)H(16)N(3))] units, giving rise to helical chains extending along the b axis. The chains are further linked through N-H?S hydrogen bonds, leading to a three-dimensional supra-molecular network.

SUBMITTER: Wang J 

PROVIDER: S-EPMC3414171 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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catena-Poly[[(2-{[2-(dimethyl-ammonio)-eth-yl]imino-meth-yl}pyridine-κ(2)N,N')bis-(thio-cyanato-κN)manganese(II)]-μ-thio-cyanato-κ(2)N:S].

Wang Jun J   Zhu Wubiao W   Li Jichang J  

Acta crystallographica. Section E, Structure reports online 20120728 Pt 8

In the title one-dimensional coordination polymer, [Mn(NCS)(3)(C(10)H(16)N(3))](n), the Mn(II) atom is coordinated by an N,N'-bidentate Schiff base and four thio-cyanate ligands in a distorted octa-hedral N(5)S geometry. Bridging thio-cyanate ligands inter-connect adjacent [Mn(NCS)(2)(C(10)H(16)N(3))] units, giving rise to helical chains extending along the b axis. The chains are further linked through N-H⋯S hydrogen bonds, leading to a three-dimensional supra-molecular network. ...[more]

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